不同类型有机物的光催化降解半导体光催化剂大多是n型半导体材料(当前以TiO2使用***广泛),具有区别于金属或绝缘物质的特别的能带结构,即在价带和导带之间存在一个禁带。由于半导体的光吸收阈值与带隙具有公式K=1240/Eg(eV)的关系,因此常用的宽带隙半导体的吸收波长阈值大都在紫外区域。
在光照下,如果光子的能量大于半导体禁带宽度,其价带上的电子(e-)就会被激发到导带上,同时在价带上产生空穴(h+)。当存在合适的俘获剂、表面缺陷或者其他因素时,电子和空穴的复合得到***,就会在催化剂表面发生氧化—还原反应。
价带空穴是良好的氧化剂,导带电子是良好的还原剂,在半导体光催化反应中,一般与表面吸附的H2O、O2反应生成˙OH和超氧离子O2-,能够把各种有机物直接氧化成CO2、H2O等无机小分子,电子也具有强还原性,可以还原吸附在其表面的物质。激发态的导带电子和价带空穴能重新合并,并产生热能或其他形式散发掉。
氧化性强:
半导体光催化具有氧化性强的特点,对臭氧难以氧化的某些有机物如、四氯化炭、、都能有效地加以分解,所以对难以降解的有机物具有特别意义,光催化的有效氧化剂是羟基自由基(OH-)和超氧离子自由基(O2-、0-),其氧化性高于常见的臭氧、***、次氯酸等。
***节能:
光催化氧化利用人工紫外线灯管产生的真空波紫外光作为能源来活化光催化剂,驱动氧化—还原反应,电能消耗低,而且光催化剂在反应过程中并不消耗,利用空气中的氧作为氧化剂,有效地降解******废臭气体、节约能源成为光催化节约能源的特点。
运行维护简单:
设备构成精简、运行简单,只需要设置风机即可,无需专人管理和日常维护。
光氧催化设备九大优点
一、***除恶臭:能***去除挥发性有机物(VOC)、***、氨气、硫醇类、苯系物等主要污染物,以及各种恶臭味,净化、脱臭效率***高可达99%以上,净化、脱臭效果大大超过1993年颁布的恶臭污染物排放标准(GB14554-93).
二、无需添加任何物质:只需要设置相应的排风管道和排风动力,使工业废气通过本设备进行分解净化,无需添加任何物质参与化学反应。
三、适应性强:可适应高浓度,大气量,不同工业废气物质的净化处理,可每天24小时连续工作,运行稳定可靠。
四、性价比高:灯管寿命长,灯管寿命12000小时以上,是传统UV灯管的8倍。
五、运行成本低:本设备无任何机械动作,无噪音,无需专人管理和日常维护,只需作定期检查,本设备能耗低,(每处理10000立方米/小时,仅耗电约7.5度电能),设备风阻极低<400pa,可节约大量排风动力能耗。
六、无需预处理:工业废气无需进行特殊的预处理,如加温、加湿等,设备工作环境温度在摄氏-20℃-60℃之间,湿度在30%-98%、PH值在3-11之间均可正常工作。
七、设备占地面积小,自重轻:适合于布置紧凑、场地狭小等特殊条件,设备占地面积<1平方米/处理10000m3/h风量。
八、优质进口材料制造:防火、防腐蚀性能高,性能稳定,使用寿命长。
九、环保科技产品:采用***技术理念,可彻底分解工业废气中******物质,并能达到***的净化效果,经分解后的气体,可完全达到无害化排放,***产生二次污染,同时达到***消***菌的作用。
喷淋塔工作原理
酸雾废气由风管引入净化塔,经过填料层,废气与***吸收液进***液两相充分接触吸收中和反应,酸雾废气经过净化后,再经除雾板脱水除雾后由风机排入大气。吸收液在塔底经水泵增压后在塔顶喷淋而下,***后回流至塔底循环使用。净化后的酸雾废气达到广东省地方排放标准的排放要求,低于排放标准。The photocatalytic photocatalysts for photocatalytic degradation of different types of organic compounds are mostly n type semiconductor materials (currently used most widely in TiO2), with a special band structure different from metal or insulating material, that is, a band gap exists between valence band and guide band. Due to the relati***hip between the optical absorption threshold of semiconductors and the band gap with formula K=1240/Eg (eV), the absorption w***elength threshold of the commonly used broadband gap semiconductors is mostly in the ultr***iolet region.
In light, if the energy of the photon is greater than the width of the semiconductor band, the electron (e-) on the valence band is excited to the guide band, and a hole (h+) is produced on the valence band. When there are suitable trapping agents, surface defects, or other factors, the recombination of electr*** and holes is suppressed, and the oxidation - reduction reaction will occur on the surface of the catalyst.
The valence band hole is a good oxidizer. The conduction band electron is a good reducing agent. In the semiconductor photocatalytic reaction, the reaction of H2O and O2, which is adsorbed on the surface, produces OH and O2-, which can directly oxidize various organic compounds into ***all inorganic molecules such as CO2, H2O and so on. The electr*** also h***e strong reducibility and can be reduced to them by reduction. A surface material. The conduction band electr*** and valence band holes in the excited state can be recombined and generate heat or other forms.
Strong oxidation:
Semiconductor photocatalysis has the characteristics of strong oxidation, which can be effectively decomposed for some organic compounds, such as four chlorinated carbon, which are difficult to oxidize by ozone, so it is of special significance to the difficult to degrade organic matter. The effective oxidizing agent for photocatalytic oxidation is the hydroxyl radical (OH-) and the superoxide radical (O2-, 0-), and its oxidation Sex is higher than ozone, hydrogen peroxide, hypochlorite and so on.
High efficiency and energy s***ing:
The photocatalytic oxidation uses the vacuum ultr***iolet light produced by the artificial ultr***iolet lamp as energy to activate the photocatalyst, which drives the oxidation reduction reaction, the energy c***umption is low, and the photocatalyst is not c***umed during the reaction process, and the oxygen in the air is used as the oxidant to effectively reduce the toxic and harmful odor gas and s***e energy. It is the characteristic of photocatalytic energy s***ing.
The operation and maintenance is simple:
The equipment is simple and simple to operate. It only needs to set up a fan, and no need for personal management and routine maintenance.
Nine advantages of optical oxygen catalytic equipment
One, efficient odor removal: the efficiency of removal of volatile organic compounds (VOC), hydrogen sulfide, ammonia, mercaptan, benzene series and other major pollutants, as well as the odor of all kinds of odor, is more than 99% of the efficiency of purification and deodorization. The effect of purification and deodorization is much more than the emission standard of odor pollutants (GB14554-93) issued in 1993.
Two, no need to add any material: only need to set the corresponding exhaust pipe and exhaust power to make industrial exhaust gas through this equipment to decompose and purify, without adding any material to participate in chemical reaction.
Three. Strong adaptability: it can be used to purify high concentration, air quantity and different industrial waste gases. It can work continuously 24 hours a day, and runs stably and reliably.
Four, high cost performance: long tube life, lamp life more than 12000 hours, is 8 times the traditional UV lamp.
Five, low operating cost: the equipment has no mechanical action, no noise, no special management and daily maintenance, only a regular inspection, low energy c***umption of this equipment, (10000 cubic meters per hour per hour, only 7.5 kilowatt hours power c***umption), the equipment wind resistance is very low < 400pa, can s***e a lot of exhaust power energy c***umption.
Six, no need to pretreat: industrial waste gas needs no special pretreatment, such as heating and humidification, the working environment temperature of the equipment is between -20 C and 60 C, the humidity is between 30% to 90% and the pH value is 3-11.
Seven, the equipment has ***all area and light self weight: it is suitable for the special conditi*** such as compact layout, ***all space and so on. The equipment covers an area of less than 1 square meters / 10000m3/h air volume.
Eight. High quality imported materials manufacture: high fire-retardant, anti-corrosion performance, stable performance and long service life.
Nine, environmental protection and technology products: using advanced technology concept, it can completely decompose toxic and harmful substances in industrial waste gas and achieve perfect purification effect. After decomposed gas, it can completely achieve harmless emission, never produce two pollution, and achieve effective disinfection and sterilization.
Working principle of sprinkler tower
The acid fog waste gas is introduced into the purifying tower by the wind pipe. The gas and liquid two phase absorption neutralization reaction is carried out by the exhaust gas and the sodium hydroxide absorption liquid. The acid mist exhaust gas is purified and then drained into the atmosphere by the dehydration of the mist removal plate and the mist eliminator. The absorption liquid is pressurized by the pump at the bottom of the tower and then sprayed down at the top of the tower. Finally, it is recycled to the bottom of the tower for recycling. After purification, the waste gas of acid mist reaches the discharge standard of local discharge standard in Guangdong, and is lower than the discharge standard.